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Journal Articles

Electrochemical studies of uranium (IV) in an ionic liquid-DMF mixture to build a redox flow battery using uranium as an electrode active material

Ouchi, Kazuki; Komatsu, Atsushi; Takao, Koichiro*; Kitatsuji, Yoshihiro; Watanabe, Masayuki

Chemistry Letters, 50(6), p.1169 - 1172, 2021/06

https://doi.org/10.1246/cl.210060
 Times Cited Count：1 Percentile：6.77(Chemistry, Multidisciplinary)

The electrochemical behavior of uranium (IV) tetrachloride in ionic liquid-DMF mixture was studied for first time in order to build a redox flow battery (RFB) using U as an electrode active material. We found a quasi-reversible U$$^{III}$$/U$$^{IV}$$ couple that could be applied to the anode reaction of the RFB.

JAEA Reports

Chlorination-Distillation Processing of Irradiated Uranium Dioxide Fuel

JAERI-M 5878, 124 Pages, 1974/10

JAERI-M-5878.pdf:3.98MB

no abstracts in English

Oral presentation

Electrochemical reaction of Uranium(IV) chloride in an ionic liquid-DMF mixture

Ouchi, Kazuki; Komatsu, Atsushi; Takao, Koichiro*; Kitatsuji, Yoshihiro; Watanabe, Masayuki

no journal, , 

The electrode reaction of uranium (IV) tetrachloride in an ionic liquid-DMF mixture was studied in order to build a redox flow battery (RFB) using U as an electrode active material. We found the quasi-reversible U(III)/U(IV) reaction that the formal potential is almost constant at -1.559 $$pm$$ 0.003 V. This reaction could be applied to the negative electrode reaction of the RFB.

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